| 1963 | 48 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini T55 996 S4 | P | Dunlop | — | — | retired | 50 | José Rosinski / Christian Bino Heins |
| 1963 | 48 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini T55 996 S4 | P | Dunlop | — | — | retired | 50 | José Rosinski / Christian Bino Heins |
| 1963 | 49 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini T55 996 S4 | P | Dunlop | — | — | retired | 63 | René Richard / Piero Frescobaldi |
| 1963 | 49 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini T55 996 S4 | P | Dunlop | — | — | retired | 63 | René Richard / Piero Frescobaldi |
| 1963 | 50 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini T55 996 S4 | P | Dunlop | — | — | retired | 227 | Bernard Boyer / Guy Verrier |
| 1963 | 50 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini T55 996 S4 | P | Dunlop | — | — | retired | 227 | Bernard Boyer / Guy Verrier |
| 1964 | 46 | Société des Automobiles Alpine | Alpine M64 | Renault Gordini T55B 1149 S4 | P | Dunlop | 17. | 7. | classified | 291 | Roger de Lageneste / Henry Morrogh |
| 1964 | 47 | Société des Automobiles Alpine | Alpine M64 | Renault Gordini T55A 1001 S4 | P | Dunlop | — | — | not_classified | 230 | Mauro Bianchi / Jean Vinatier Jr |
| 1964 | 51 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini 1108 S4 | GT | — | — | — | — | 0 | Jacques Feret / Pierre Orsini |
| 1964 | 51 | Société des Automobiles Alpine | Alpine M63 | Renault Gordini 1108 S4 | GT | — | — | — | — | 0 | Jacques Feret / Pierre Orsini |
| 1964 | 54 | Société des Automobiles Alpine | Alpine M64 | Renault Gordini T55B 1149 S4 | P | Dunlop | — | — | retired | 133 | Philippe Vidal / Henri Grandsire |
| 1964 | 59 | Société des Automobiles Alpine | Alpine M63b | Renault Gordini T55A 1001 S4 | P | Dunlop | 20. | 8. | classified | 284 | Roger Masson / Teodoro Zeccoli |
| 1965 | 46 | Société des Automobiles Alpine | Alpine M65 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 32 | Mauro Bianchi / Henri Grandsire |
| 1965 | 47 | Société des Automobiles Alpine | Alpine M65 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 196 | Roger de Lageneste / Jean Vinatier Jr |
| 1965 | 50 | Société des Automobiles Alpine | Alpine M64 | Renault Gordini T55B 1149 S4 | P | Dunlop | — | — | retired | 116 | Philippe Vidal / Peter Revson |
| 1965 | 51 | Société des Automobiles Alpine | Alpine M64 | Renault Gordini T55B 1149 S4 | P | Dunlop | — | — | retired | 148 | Roger Masson / Guy Verrier |
| 1965 | 55 | Société des Automobiles Alpine | Alpine GT4 M64 | Renault 1108 S4 | GT | Dunlop | — | — | retired | 196 | Jacques Cheinisse / Jean-Pierre Hanrioud |
| 1965 | 61 | Société des Automobiles Alpine | Alpine M63/64 | Renault Gordini T55A 1001 S4 | P | Dunlop | — | — | retired | 187 | Pierre Monneret / Robert Bouharde |
| 1966 | 44 | Ecurie Savin-Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | 11. | 8. | classified | 306 | Jacques Cheinisse / Roger de Lageneste |
| 1966 | 44 | Ecurie Savin-Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | 11. | 8. | classified | 306 | Jacques Cheinisse / Roger de Lageneste |
| 1966 | 45 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1292 S4 | P | Dunlop | 12. | 9. | classified | 306 | Guy Verrier / Robert Bouharde |
| 1966 | 45 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1292 S4 | P | Dunlop | 12. | 9. | classified | 306 | Guy Verrier / Robert Bouharde |
| 1966 | 46 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | 13. | 10. | classified | 305 | Mauro Bianchi / Jean Vinatier Jr |
| 1966 | 46 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | 13. | 10. | classified | 305 | Mauro Bianchi / Jean Vinatier Jr |
| 1966 | 47 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 217 | Berndt Jansson / Pauli Toivonen |
| 1966 | 47 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 217 | Berndt Jansson / Pauli Toivonen |
| 1966 | 55 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | P | Goodyear | — | — | retired | 118 | André de Cortanze / Jean-Pierre Hanrioud |
| 1966 | 55 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | P | Goodyear | — | — | retired | 118 | André de Cortanze / Jean-Pierre Hanrioud |
| 1966 | 56 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | P | Goodyear | — | — | — | 0 | Jean-François Piot / Alain Le Guellec |
| 1966 | 56 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | P | Goodyear | — | — | — | 0 | Jean-François Piot / Alain Le Guellec |
| 1966 | 62 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | 9. | 7. | classified | 311 | Henri Grandsire / Léo Cella |
| 1966 | 62 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | 9. | 7. | classified | 311 | Henri Grandsire / Léo Cella |
| 1967 | 45 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58C 1470 S4 | P | Michelin | 13. | 10. | classified | 311 | Mauro Bianchi / Jean Vinatier Jr |
| 1967 | 45 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58C 1470 S4 | P | Michelin | 13. | 10. | classified | 311 | Mauro Bianchi / Jean Vinatier Jr |
| 1967 | 46 | Société des Automobiles Alpine (F) - Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Michelin | 9. | 7. | classified | 321 | Henri Grandsire / José Rosinski |
| 1967 | 46 | Société des Automobiles Alpine (F) - Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Michelin | 9. | 7. | classified | 321 | Henri Grandsire / José Rosinski |
| 1967 | 47 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 219 | Jean-Claude Andruet / Robert Bouharde |
| 1967 | 47 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 219 | Jean-Claude Andruet / Robert Bouharde |
| 1967 | 48 | Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Michelin | 12. | 9. | classified | 312 | Roger de Lageneste / Jacques Cheinisse |
| 1967 | 48 | Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Michelin | 12. | 9. | classified | 312 | Roger de Lageneste / Jacques Cheinisse |
| 1967 | 49 | Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Michelin | 10. | 8. | classified | 318 | André de Cortanze / Alain Le Guellec |
| 1967 | 49 | Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Michelin | 10. | 8. | classified | 318 | André de Cortanze / Alain Le Guellec |
| 1967 | 55 | North American Racing Team | Alpine M64 | Renault Gordini T58B 1005 S4 | P | Dunlop | — | — | retired | 201 | Jean-Luc Thérier / François Chevalier |
| 1967 | 56 | Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58B 1005 S4 | P | Michelin | — | — | retired | 204 | Gérard Larrousse / Patrick Depailler |
| 1967 | 56 | Ecurie Savin Calberson | Alpine A210 | Renault Gordini T58B 1005 S4 | P | Michelin | — | — | retired | 204 | Gérard Larrousse / Patrick Depailler |
| 1967 | 58 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 67 | Philippe Vidal / Léo Cella |
| 1967 | 58 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | P | Dunlop | — | — | retired | 67 | Philippe Vidal / Léo Cella |
| 1968 | 27 | Ecurie Savin-Calberson | Alpine A220 | Renault Gordini T62 2997 V8 à 90° | SP | Michelin | — | — | retired | 257 | Mauro Bianchi / Patrick Depailler |
| 1968 | 28 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2996 V8 à 90° | SP | Michelin | — | — | retired | 59 | Henri Grandsire / Gérard Larrousse |
| 1968 | 29 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2996 V8 à 90° | SP | Michelin | — | — | retired | 185 | Jean Guichet / Jean-Pierre Jabouille |
| 1968 | 30 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2996 V8 à 90° | SP | Michelin | 8. | 6. | classified | 297 | André de Cortanze / Jean Vinatier Jr |
| 1968 | 51 | Bernard Collomb | Alpine A110 | Renault Gordini 1289 S4 | GT | Dunlop | — | — | retired | 167 | Bernard Collomb / François Lacarrau |
| 1968 | 52 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | SP | Dunlop | 10. | 8. | classified | 287 | Jean-Luc Thérier / Bernard Tramont |
| 1968 | 52 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | SP | Dunlop | 10. | 8. | classified | 287 | Jean-Luc Thérier / Bernard Tramont |
| 1968 | 53 | Trophée Le Mans | Alpine A210 | Renault Gordini T58A 1296 S4 | SP | Dunlop | 11. | 9. | classified | 281 | Christian Ethuin / Bob Wollek |
| 1968 | 53 | Trophée Le Mans | Alpine A210 | Renault Gordini T58A 1296 S4 | SP | Dunlop | 11. | 9. | classified | 281 | Christian Ethuin / Bob Wollek |
| 1968 | 55 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | SP | Dunlop | 14. | 10. | classified | 272 | Jean-Pierre Nicolas / Jean-Claude Andruet |
| 1968 | 55 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | SP | Dunlop | 14. | 10. | classified | 272 | Jean-Pierre Nicolas / Jean-Claude Andruet |
| 1968 | 56 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | SP | Dunlop | — | — | retired | 71 | Jean-Louis Marnat / Jean-François Gerbault |
| 1968 | 56 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | SP | Dunlop | — | — | retired | 71 | Jean-Louis Marnat / Jean-François Gerbault |
| 1968 | 57 | Ecurie Savin-Calberson | Alpine A210 | Renault Gordini T58C 1470 S4 | SP | Dunlop | 9. | 7. | classified | 289 | Alain Le Guellec / Alain Serpaggi |
| 1968 | 57 | Ecurie Savin-Calberson | Alpine A210 | Renault Gordini T58C 1470 S4 | SP | Dunlop | 9. | 7. | classified | 289 | Alain Le Guellec / Alain Serpaggi |
| 1968 | 61 | Ecurie Léopard | Alpine A110 | Renault 1255 S4 | GT | Dunlop | — | — | not_classified | 215 | Joseph Bourdon / Maurice Nusbaumer |
| 1969 | 28 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2997 V8 à 90° | SP | Michelin | — | — | retired | 133 | Jean Vinatier Jr / André de Cortanze |
| 1969 | 29 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2997 V8 à 90° | SP | Michelin | — | — | retired | 209 | Patrick Depailler / Jean-Pierre Jabouille |
| 1969 | 30 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2997 V8 à 90° | SP | Michelin | — | — | retired | 48 | Jean-Claude Andruet / Henri Grandsire |
| 1969 | 31 | Société des Automobiles Alpine | Alpine A220 | Renault Gordini T62 2997 V8 à 90° | SP | Michelin | — | — | retired | 160 | Jean-Pierre Nicolas / Jean-Luc Thérier / Henri Grandsire |
| 1969 | 45 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58C 1470 S4 | SP | Dunlop | — | — | retired | 242 | Jean-Claude Killy / Bob Wollek |
| 1969 | 45 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58C 1470 S4 | SP | Dunlop | — | — | retired | 242 | Jean-Claude Killy / Bob Wollek |
| 1969 | 46 | Ecurie Savin-Calberson | Alpine A210 | Renault Gordini T58CI 1470 S4 | SP | Michelin | — | — | retired | 1 | Alain Le Guellec / Bernard Tramont |
| 1969 | 46 | Ecurie Savin-Calberson | Alpine A210 | Renault Gordini T58CI 1470 S4 | SP | Michelin | — | — | retired | 1 | Alain Le Guellec / Bernard Tramont |
| 1969 | 49 | Trophée Le Mans Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | SP | Dunlop | — | — | retired | 97 | Jacques Foucteau / Patrice Compain |
| 1969 | 49 | Trophée Le Mans Alpine | Alpine A210 | Renault Gordini T58A 1296 S4 | SP | Dunlop | — | — | retired | 97 | Jacques Foucteau / Patrice Compain |
| 1969 | 50 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | SP | Dunlop | 12. | 6. | classified | 292 | Alain Serpaggi / Christian Ethuin |
| 1969 | 50 | Société des Automobiles Alpine | Alpine A210 | Renault Gordini T58B 1005 S4 | SP | Dunlop | 12. | 6. | classified | 292 | Alain Serpaggi / Christian Ethuin |
| 1971 | 52 | Ecurie Léopard | Alpine A110-1600 | Renault 1596 S4 | GTS | — | — | — | — | 0 | Joseph Bourdon / Maurice Nusbaumer |
| 1977 | 87 | Bernard Decure | Alpine Renault A310 | Renault PRV ZNS4 2664 V6 à 90° | GTP | Michelin | — | — | retired | 4 | Bernard Decure / Jean-Luc Thérier / Cochise (Jacky Cauchy) |
| 1994 | 60 | Societé Legeay Sports Méca. | Alpine A610 Turbo | PRV 2975 V6 à 90° Bi-turbo | LM GT2 | Michelin | 13. | 5. | classified | 272 | Benjamin Roy / Luc Galmard / Jean-Claude Police |
| 2013 | 36 | Signatech-Alpine | Alpine A450 | Alpine (Nissan Nismo) 4494 V8 à 90° | LM P2 | Michelin | 14. | 8. | classified | 317 | Pierre Ragues / Nelson Panciatici / Tristan Gommendy |
| 2014 | 36 | Signatech-Alpine | Alpine A450 B | Alpine (Nissan Nismo) 4494 V8 à 90° | LM P2 | Dunlop | 7. | 3. | classified | 355 | Paul-Loup Chatin / Nelson Panciatici / Oliver Webb |
| 2015 | 36 | Signatech-Alpine | Alpine A450b | Alpine (Nissan Nismo) 4494 V8 à 90° | LM P2 | Dunlop | — | — | retired | 110 | Paul-Loup Chatin / Nelson Panciatici / Vincent Capillaire |
| 2015 | 36R | Signatech-Alpine | Alpine A450b | Alpine (Nissan Nismo) 4494 V8 à 90° | LM P2 | Dunlop | — | — | — | 0 | — |
| 2016 | 35 | Baxi DC Racing Alpine | Alpine A460 | Alpine (Nissan Nismo) 4494 V8 à 90° | LM P2 | Dunlop | — | — | retired | 234 | David Cheng / Ho Pin Tung / Nelson Panciatici |
| 2016 | 36 | Signatech-Alpine | Alpine A460 | Alpine (Nissan Nismo) 4494 V8 à 90° | LM P2 | Dunlop | 5. | 1. | classified | 357 | Gustavo Menezes / Nicolas Lapierre / Stéphane Richelmi |
| 2017 | 35 | Signatech-Alpine | Alpine A470 | Gibson GK428 4200 V8 à 90° | LM P2 | Dunlop | 4. | 3. | classified | 362 | Nelson Panciatici / Pierre Ragues / André Negrao |
| 2017 | 36 | Signatech-Alpine | Alpine A470 | Gibson GK428 4200 V8 à 90° | LM P2 | Dunlop | 10. | 8. | classified | 351 | Gustavo Menezes / Romain Dumas / Matthew Rao |
| 2018 | 36 | Signatech-Alpine | Alpine A470 | Gibson GK428 4200 V8 à 90° | LM P2 | Dunlop | 5. | 1. | classified | 367 | Nicolas Lapierre / Pierre Thiriet / André Negrao |
| 2019 | 36 | Signatech-Alpine | Alpine A470 | Gibson GK428 4200 V8 à 90° | LM P2 | Michelin | 6. | 1. | classified | 368 | Nicolas Lapierre / Pierre Thiriet / André Negrao |
| 2020 | 36 | Signatech-Alpine | Alpine A470 | Gibson GK428 4200 V8 à 90° | LM P2 | Michelin | 8. | 4. | classified | 367 | Thomas Laurent / André Negrao / Pierre Ragues |
| 2021 | 36 | Alpine ELF Matmut | Alpine 480 | Gibson GL458 4496 V8 à 90° | LMH | Michelin | 3. | 3. | classified | 367 | André Negrao / Nicolas Lapierre / Matthieu Vaxivière |
| 2022 | 36 | Alpine ELF Matmut | Alpine 480 | Gibson GL458 4496 V8 à 90° | LMH | Michelin | 23. | 5. | classified | 362 | André Negrao / Nicolas Lapierre / Matthieu Vaxivière |
| 2024 | 35 | Alpine Endurance Team | Alpine A424 | Mecachrome LMC 3400 V6 à 90° Turbo Hybride | HYPERCAR | Michelin | — | — | retired | 75 | Ferdinand Habsburg-Lothringen / Paul-Loup Chatin / Charles Milesi |
| 2024 | 35 | Alpine Endurance Team | Alpine A424 | Mecachrome LMC 3400 V6 à 90° Turbo Hybride | HYPERCAR | Michelin | — | — | retired | 75 | Ferdinand Habsburg-Lothringen / Paul-Loup Chatin / Charles Milesi |
| 2024 | 36 | Alpine Endurance Team | Alpine A424 | Mecachrome LMC 3400 V6 à 90° Turbo Hybride | HYPERCAR | Michelin | — | — | retired | 88 | Nicolas Lapierre / Mick Schumacher / Matthieu Vaxivière |
| 2024 | 36 | Alpine Endurance Team | Alpine A424 | Mecachrome LMC 3400 V6 à 90° Turbo Hybride | HYPERCAR | Michelin | — | — | retired | 88 | Nicolas Lapierre / Mick Schumacher / Matthieu Vaxivière |
| 2025 | 35 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 9. | 9. | classified | 385 | Ferdinand Habsburg-Lothringen / Paul-Loup Chatin / Charles Milesi |
| 2025 | 35 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 9. | 9. | classified | 385 | Ferdinand Habsburg-Lothringen / Paul-Loup Chatin / Charles Milesi |
| 2025 | 36 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 10. | 10. | classified | 384 | Frédéric Makowiecki / Mick Schumacher / Jules Gounon |
| 2025 | 36 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 10. | 10. | classified | 384 | Frédéric Makowiecki / Mick Schumacher / Jules Gounon |
| 2026 | 35 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 6. | 6. | classified | 381 | Charles Milesi / Antonio Félix da Costa / Ferdinand Habsburg-Lothringen |
| 2026 | 35 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 6. | 6. | classified | 381 | Charles Milesi / Antonio Félix da Costa / Ferdinand Habsburg-Lothringen |
| 2026 | 36 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 10. | 10. | classified | 379 | Frédéric Makowiecki / Jules Gounon / Victor Martins |
| 2026 | 36 | Alpine Endurance Team | Alpine A424 | Mecachrome 3400 V6 à 90° Turbo Hybride | Hypercar | Michelin | 10. | 10. | classified | 379 | Frédéric Makowiecki / Jules Gounon / Victor Martins |